Materials that melt and freeze to store heat

Phase Change Materials (PCM)

Organic, salt-hydrate, eutectic and metallic PCMs — choosing the melting point, latent heat and encapsulation.

Deep-dive · 35 pages

A PCM is chosen first by its melting temperature, which should sit just above the delivery temperature the user needs, and then by latent heat, density, conductivity, stability, safety and price.

PCMs are used in macro-capsules, tube-and-shell modules, slurries or composite boards. Graphite and metal fins compensate for low conductivity.

Key facts

Paraffins
≈ 5–120 °C · ≈ 150–250 kJ/kg
Salt hydrates
≈ 10–120 °C · high density
Nitrates / eutectics
≈ 120–350 °C
Metallic
≈ 300–800 °C · high conductivity

PCM families6

  • Organic phase-change materials
  • Paraffin-based materials
  • Salt hydrates
  • Eutectic mixtures
  • Metallic and high-temperature PCMs
  • Encapsulated PCM modules

Selection criteria7

  • Melting point vs delivery temperature
  • Latent heat per kg and per m³
  • Thermal conductivity
  • Cycling and chemical stability
  • Supercooling and segregation
  • Flammability and toxicity
  • Cost and availability

Formats5

  • Encapsulated spheres and slabs
  • Shell-and-tube PCM exchangers
  • PCM in containers / thermal boxes
  • Composite PCM-graphite
  • PCM slurries for cooling

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Related topics

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