Store energy in a phase change

Latent Heat Storage

Phase-change materials absorb and release heat as they melt and freeze — compact storage at a nearly constant temperature.

Deep-dive · 35 pages

When a material melts it absorbs its latent heat of fusion without rising in temperature; it gives the heat back as it solidifies. That makes latent storage compact and ideal when the user needs a steady temperature.

Paraffins and organic PCMs work from about 5 to 120 °C, salt hydrates in a similar range, and salts, eutectics and metallic PCMs at several hundred °C. Low thermal conductivity and encapsulation are the main design challenges.

Key facts

Equation
Q = m · (cp,s ΔT₁ + L + cp,l ΔT₂)
Paraffin L
≈ 150–250 kJ/kg
Strength
Near-constant delivery temperature
Maturity
Commercial / emerging

Phase-change materials6

  • Organic phase-change materials
  • Paraffin-based materials
  • Salt hydrates
  • Eutectic mixtures
  • Metallic and high-temperature PCMs
  • Encapsulated PCM modules

Applications6

  • Building temperature stabilisation
  • Compact process-heat buffers
  • Industrial waste heat recovery
  • Cold-chain and cooling storage
  • Electronics and battery thermal management
  • High-temperature PCM for steam

Design issues6

  • Low thermal conductivity — fins, graphite, heat pipes
  • Supercooling and phase segregation
  • Encapsulation and container compatibility
  • Volume change on melting
  • Long-term cycling stability
  • Fire properties of organic PCM

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Related topics

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